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Ch. 16: Origin of the Diamond

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ORIGIN OF THE DIAMOND 365
tention to the methods or method by which Nature created the compact and beautiful crystal, and inci­dentally to enquire how and from what source she ob­tained the necessary carbon. As to the means by which the transformation was effected, they have succeeded so far that they can make the crystals in microscopic size, and thereby illustrate in a general way the larger methods of Nature; but whence she gathered the supply of material for her furnaces is still an open question.
The process of making diamonds as described by Sir William Crookes is to select pure iron free from sulphur, silicon, phosphorus, etc., and pack it in a carbon crucible with pure charcoal from sugar. This must be put into the body of an electric furnace. After heating for a few minutes to a temperature above 4,000 deg. C, at which heat the iron melts and volatilizes, the current is stopped, and the crucible plunged into cold water and held there until it sinks below a red heat.
The outer layer of iron, solidified by the sudden cooling, holds the molten interior in a rigid enclosure. The inner liquid expands as it solidifies, thus creating an enormous pressure, under the stress of which the dissolved carbon separates out in microscopic crystals which though small are veritable diamonds.
Crookes places the theoretical melting point of carbon at 4,400 deg. C. absolute, and the melting pressure as 16.6 atmospheres. He found what he believed to be diamonds, in residue obtained by exploding cordite in closed steel cylinders. This meant a pressure of 8,000 atmospheres and a temperature of about 5,400 deg. absolute.
Prof. Moissan first crystallized carbon artificially.
Ch. 16: Origin of the Diamond Page of 448 Ch. 16: Origin of the Diamond
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