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Ch. 8: Diamond - Physical and Chemical Properties

Ch. 8: Diamond - Physical and Chemical Properties Page of 171 Ch. 8: Diamond - Physical and Chemical Properties Text size:minus plus Restore normal size   Mail page  Print this page
MELTING-POINT OF CARBON
Carbon and arsenic are the only two elements that have a melting-point above the boiling-point ; and among compounds carbonic acid and fluoride of silicium are the only other bodies with similar properties. Now the melting-point of arsenic is about 1-2 times its absolute boiling-point. With carbonic acid and fluoride of silicium the melting-points are about i-i times their boiling-points. Applying these ratios to carbon, we find that its melting-point would be about 44000.
Therefore, assuming the following data :
Boiling-point..............38700 Ab.
Melting-point..............44000
Critical temperature.......5800°
Critical pressure...........2320 Ats.
the Rankine or Van der Waals formula, calculated from the boiling-point and critical data, would be as follows :
log. P=io-ii-39120/T,
in
Ch. 8: Diamond - Physical and Chemical Properties Page of 171 Ch. 8: Diamond - Physical and Chemical Properties
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