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Book V: Underground Mining

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BOOK V.
111
schist, marble, and also in stone which easily melts in fire of the second
degree, and which is sometimes so porous that it seems completely decomposed. Lastly, gold is found in pyrites, though rarely in large quantities.
When considering silver ores other than native silver, those ores are
Arsenical Minerals. Metallic arsenic was unknown, although it has been maintained that a substance mentioned by Albertus Magnus (De Rebus Metallicis) was the
metallic form. Agricola, who was familiar with all Albertus's writings, makes no mention
of it, and it appears to us that the statement of Albertus referred only to the oxide from
sublimation. Our word " arsenic " obviously takes root in the Greek for orpiment, which
was also used by Pliny (xxxiv, 56) as arrhenicum, and later was modified to arsenicum
by the Alchemists, who applied it to the oxide. Agricola gives the following in Bermannus (p.
448), who has been previously discussing realgar and orpiment :—" Ancori : Avicenna
" also has a White variety. Bermannus : I cannot at all believe in a mineral of a white
" colour ; perhaps he was thinking of an artificial product ; there are two which the Alchemists
" make, one yellow and the other white, and they are accounted the most powerful poisons
" to-day, and are called only by the name arsenicum." In De Natura Fossilium (p. 21g) is
described the making of " the white variety" by sublimating orpiment, and also it is noted
that realgar can be made from orpiment by heating the latter for five hours in a sealed
crucible. In De Re Metallica (Book X.), he refers to auripigmentum facticum, and no doubt
means the realgar made from orpiment. The four minerals of arsenic base mentioned by
Agricola were :—
We are somewhat uncertain as to the identification of the last. The yellow and red sulphides, however, were well known to the Ancients, and are described by Aristotle, Theophrastus
(71 and 89), Dioscorides (v, 81), Pliny (xxxm, 22, etc.) ; and Strabo (xn, 3, 40) mentions
a mine of them near Pompeiopohs, where, because of its poisonous character none but slaves
were employed. The Ancients believed that the yellow sulphide contained gold—hence
the name auripigmentum, and Pliny describes the attempt of the Emperor Caligula to extract
the gold from it, and states that he did obtain a small amount, but unprofitably. So late
a mineralogist as Hill (1750) held this view, which seemed to be general. Both realgar and
orpiment were important for pigments, medicinal purposes, and poisons among the Ancients.
In addition to the above, some arsenic-cobalt minerals are included under cadmia.
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