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Ch. 3: Minerals: Chemical Properties

Ch. 3: Minerals: Chemical Properties Page of 515 Ch. 3: Minerals: Chemical Properties Text size:minus plus Restore normal size   Mail page  Print this page
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A POPULAR TREATISE ON GEMS.
clear glass, milk-white when cold; the sulphate is very difficultly fusible. Both strongly heated at the point of the blue flame impart a green tinge to the outer flame. When combined with silica it cannot be well discovered by the blowpipe. In solution, salts of baryta yield, with sul­phuric acid or solution of sulphate of lime, immediately a fine white precipitate insoluble in acids or alkalies.
Strontia, the carbonate, even in thin plates, only melts on the edges, and forms cauliflower-like projections of dazzling brightness; the sulphate melts easily in the oxi­dating flame, and in the reducing flame is changed into sulphuret of strontium, which, dissolved in hydrochloric acid, and evaporated to dryness, gives a fine carmine-red color to the flame of alcohol. Strontia in solution gives a precipitate with sulphuric- acid, or with sulphate of lime, but not immediately.
Lime.—The carbonate is rendered caustic by heat, when it has alkaline properties, and readily absorbs water. The sulphate in the reducing flame changes to the sulphuret of calcium, which is also alkaline. Sulphuric acid precipi­tates lime only from very concentrated solutions; oxalic acid even from very weak ones; and silico-hydrofluoric acid not at all. As baryta and strontia also form precipitates with the first two reagents, they must previously be sepa­rated by sulphate of potassa. Chloride of calcium tinges the flame of alcohol yellowish-red.
Magnesia, alone, or as a hydrate, a carbonate, and in • some other combinations, when ignited with solution of cobalt, or the oxalate of cobalt, assumes a light-red tint. It is not precipitated from a solution either by sulphuric acid, oxalic acid, or silico-hydrofluoric acid; but phosphoric acid, with ammonia, throws down a white crystalline pre­cipitate of phosphate of ammonia and magnesia.
Alumina alone is infusible. In many combinations, when
Ch. 3: Minerals: Chemical Properties Page of 515 Ch. 3: Minerals: Chemical Properties
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