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Ch. 3: Minerals: Chemical Properties

Ch. 3: Minerals: Chemical Properties Page of 515 Ch. 3: Minerals: Chemical Properties Text size:minus plus Restore normal size   Mail page  Print this page
CHEMICAL PROPERTIES OF MINERALS.                127
be separated from each other by heat. Only the Osmium-indium strongly heated in the closed tube with saltpetre is decomposed, forming osmium acid, known from its pecu- liar pungent odor. The usual mixture of platinum grains is soluble in nitro-chloric acid, leaving osmium-iridium. From this solution the platinum is thrown down by sal-ammonia as a double chloride of platinum and ammonium. From the solution evaporated, and again diluted, with cyanide of mercury, the palladium separates as cyanide of palladium. The rhodium may be separated by its property of combining with fused bisulphate of potassa, which is not the case with platinum or iridium.
Cerium, when no iron-oxide is present, produces, with borax and salt of phosphorus, in the oxidating flame, a red. or dark-yellow glass, which becomes very pale when cold, and colorless in the reducing flame. Lanthanium oxide forms a white colorless glass; didymium, a dark amethyst­ine glass.
Iron, the peroxide and hydrated peroxide, become black . and magnetic before the blowpipe, and form, with borax or salt of phosphorus, in the oxidating flame, a dark-red glass, becoming bright-yellow when cold; and in the reducing flame, especially on adding tin, an olive-green or mountain-green glass. The peroxide colors a bead of horax contain­ing copper oxide, bluish-green ; the protoxide produces red spots. Salts of protoxide of iron form a green solution, from which potassa or ammonia throws down the protoxide as a hydrate, which is first white, then dirty-green, and finally yellowish-brown. Carbonate of lime produces no precipitate. The salts of the peroxide, on the other hand, form yellow solutions from which the peroxide is thrown down by potassa or ammonia as a flaky-brown hydrate. Carbonate of lime also causes a precipitate. • Chromium forms, with borax or salt of phosphorus, a
Ch. 3: Minerals: Chemical Properties Page of 515 Ch. 3: Minerals: Chemical Properties
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