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1000                                    Journal of Chemical Education                    August, 1927
dirt. Recipe No. 61, in which lime is employed in this manner, apparently contains some rudimentary attempt at chemical theory. Various liquids were also employed in cleaning. Perhaps the most curious and the least scientific of these cleaning methods is that described in Recipes Xo. 25 and 60 in which the pearl is given to a fowl to eat and is afterward re­covered and found to be cleaned. This set of recipes contains the first account of the manufacture of imitation pearls. Recipe No. IS describes their preparation in which shimmering scales from mica or ground selenite were incorporated in a paste made from gum, wax, mercury, and white of eggs. This was then shaped and dried, probably yielding an inferior imitation of the real thing, although the last sentence of the recipe assures us otherwise. Recipes No. 22 and 23 detail other methods of accomplish­ing the same end. The remainder of the recipes of the second group deal with the imitating of emerald, ruby, beryl, amethyst, sunstone, and other valuable gem stones. The base for nearly all of these imitations is the so-called crystal. This word in Greek is generally understood to mean quartz or rock crystal. Probably, however, its meaning in the papyrus was extended to other clear stones, notably to selenite, since the processes used depended somewhat upon having more easily corroded stones than quartz. At any rate, the first step in the manufacture of imitation precious stones, as practiced in ancient Egypt, was to treat the base used in such a way as to roughen it and to make the surface of the stones porous. Various substances and methods were used for this purpose. The heated stones were generally boiled or dipped in oil, wax, or solutions of alum, native soda, common salt, vinegar, calcium sulfide, or in mixtures of these. By this means the surface of the stone used was roughened and also, probably to some degree, mordanted for the applica­tion of dyes. After corroding or mordanting the stone in this manner some kind of a dyeing material was then applied. These latter fall into two classes, the inorganic and the organic substances. Copper salts, for example, were usually applied to form imitation emeralds from the base, while alkanet was used for red stones. Recipe No. 74 is of special interest in that it gives the method of preparing verdigris for this very purpose. This is probably the first detailed laboratory direction for the preparation of a chemical salt. Many vegetable dyes and other organic substances were employed in dyeing the treated crystal, among which were alkanet, celandine, cedar oil, pitch, and various resins. In some cases the two operations were combined in one. It is to be remarked that many of the recipes carry various detailed precautions concerning the processes, showing the presence of much experience in carrying them out. We may well question the beauty and the permanency of the imi­tation gems prepared by these methods, but probably they satisfied the people of that period. These methods of imitating precious stones 'seem
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Radcliffe. The Stockholm Papyrus.
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