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PLATINUM AND ALLIED METALS.
343
To determine the cause of these great discrepancies requires most painstaking investigation. It used to be believed that the platinum of the graywacke be­haved abnormally while the precious metals were in the gel form in the rocks. The first one to advance this theory was Schreiber, the discoverer of platinum in the Siegerland. He has doubtless some justification for this assumption, because, first, the gels have the property of appearing in finest division in the rocks, and, second, colloidal platinum solutions are known. The question whether a precious metal occurs as a gel can not be answered by a chemist but rather by a petrographer, because the gel is easily distinguished optically from crystalline bodies, and this can not be done chemically. Schreiber was really in error when he assumed that the difficulty in platinum chemistry had something to do with the gel form. If platinum is in the gel form, this can work no hardship on the chemist with the dry method, because gel is converted into the crystalline form by great heat. As it is possible to distinguish minute crystal fragments in the black specks, it is probable that in this case it is not a question of gels but of crystalline structures. * * *
There must therefore be some other reason for this discrepancy in results. It is either an error in analytical method or the original distribution of plati­num in the rock. I am loath to admit any possibility of error in the chemical work. I am inclined to agree with Pufahl that the irregular distribution of the metal, in spite of the great fineness and the most careful mixing, is accountable for incorrect averages. We are already acquainted with similar cases. * * *
It is, then, impossible to establish the average in this way. The practical in­ference from all this is that we can only depend upon actual production which is capable of being demonstrated on a small scale for experimental purposes. Only the most exacting tests on samples of 1 ton and the extraction of the con­tained platinum can guard us against error.
RUSSIA.
There is a dearth of information concerning operations in the Rus-sian platinum fields during 1914. During ordinary years the London Mining Journal contains a number of contributions on Russian plati­num, but very little news for 1914. Before the outbreak of the war the feeling was strong that Russia would produce as much, if not more, platinum in 1914 than for several years, owing in part to new dredging ventures and in part to the owners permitting more work under the leasing system. From the published figures of production this expectation was not realized.
The most important event in the Russian situation was the plac­ing early in the year of a 30 per cent ad valorem export duty on crude platinum.1 The value of crude platinum under this law is to be fixed by the council of ministers, and it is thought that it will produce a revenue of approximately $2,000,000 a year. The law was apparently passed with the expectation of bringing platinum
' Min. Jour. (London), vol. 104, p. 180, Feb. 21, 1914.